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The role of calcium chloride in refrigeration

Calcium chloride plays a significant role in the refrigeration sector, primarily due to its physical and chemical properties. It is widely used in industrial refrigeration systems, food freezing processes, and other related applications. Below is a detailed explanation of its specific functions and principles: I. As a Coolant (Heat Transfer Medium) 1. Working Principle Calcium chloride aqueous solution (brine) has a low freezing point, which decreases as the concentration increases. For example: When the calcium chloride concentration is 29.9%, the freezing point can drop to -55°C. This property allows it to remain liquid at low temperatures. It absorbs heat from the objects to be cooled through cyclic flow and then releases the heat via a refrigeration unit, enabling continuous refrigeration. 2. Application Scenarios Industrial refrigeration systems: Such as cold storage facilities and freezing workshops in food processing plants, where calcium chloride solution circulates to remove heat and maintain a low-temperature environment. Winter concrete construction: Used to cool mixing water in refrigeration equipment, preventing concrete from freezing. II. For Ice Making and Ice Melting 1. In Ice Production In large-scale ice makers, calcium chloride solution serves as a low-temperature coolant, transferring the cold energy generated by the refrigerator to ice-making molds, causing water to freeze rapidly into ice (e.g., production of block ice or flake ice). 2. For Ice and Snow Melting Solid or aqueous calcium chloride can be spread on roads or airport runways. It melts ice and snow by lowering the freezing point (similar to salting roads in winter), though its corrosiveness to metals and concrete should be noted. III. Application in Absorption Refrigeration 1. Principle of Absorption Refrigeration Systems Absorption refrigeration relies on a combination of a refrigerant (e.g., ammonia) and an absorbent. Calcium chloride can act as an absorbent (or auxiliary absorbent) to absorb ammonia, forming a solution. Heating then releases ammonia to complete the refrigeration cycle. 2. Advantages It does not require a power-consuming compressor and can be driven by waste heat (e.g., industrial waste heat, solar energy), making it suitable for energy-saving scenarios. IV. Other Refrigeration-Related Applications 1. Laboratory Low-Temperature Baths High-concentration calcium chloride solutions can create a low-temperature environment ranging from -20°C to -50°C, used for chemical experiments, material testing, etc. 2. Cold Chain Transportation As a cool storage agent, it is packaged in ice bags or cool storage boxes to provide a low-temperature transport environment for vaccines, fresh produce, etc. (utilizing the cold energy released when it solidifies). Precautions for Using Calcium Chloride Corrosiveness: Calcium chloride aqueous solution is highly corrosive to metals (e.g., steel, copper). Corrosion inhibitors must be added to the system, or corrosion-resistant materials like stainless steel or plastic should be used. Concentration Control: The concentration must be precisely adjusted according to the target temperature. Too low a concentration may cause freezing, while too high a concentration may lead to crystallization and pipeline blockage. Environmental Protection and Safety: Leakage of calcium chloride solution may contaminate soil or water sources, so sealing and recycling measures should be implemented. Solid calcium chloride is highly hygroscopic and should be stored in a sealed container. Conclusion Calcium chloride, with its low freezing point, good thermal conductivity, and cost advantages, serves as an important material for coolants and absorbents in the refrigeration field, especially in industrial and civil scenarios requiring low temperatures. Its application requires optimizing the formula based on specific working conditions while paying attention to corrosion prevention and safety issues.

01

2025/07

The role of calcium chloride in fertilizers

calcium chloride has several important roles in fertilizers, and its functions mainly focus on plant growth needs, soil improvement, and fertilizer performance optimization. The following is a detailed introduction: providing calcium nutrition promoting plant growth and development: calcium is an essential medium element for plant growth, participating in the construction of cell walls, which can enhance the stability of cell structures, promote the growth of roots and stems. For example, it can make crop roots more developed and improve the ability of crops to absorb water and nutrients. maintaining normal cell functions: it helps maintain the permeability and selectivity of the cell membrane, prevent the exudation of substances inside the cell, and ensure the normal progress of various physiological and biochemical reactions inside the cell. reducing physiological diseases: it can prevent various physiological diseases caused by calcium deficiency in plants, such as blossom end rot in tomatoes and bitter pit in apples, and improve the quality and yield of crops. improving soil properties regulating soil pH: calcium chloride is slightly acidic, which can neutralize the alkalinity of some soils, improve the pH value of the soil, and create a more suitable soil environment for plant growth. increasing soil aggregate structure: calcium ions can combine with colloids in the soil to promote the formation of soil aggregate structure, improve soil air permeability and water retention, and enhance soil fertility. reducing the harm of soil salinity: using calcium chloride in saline-alkali land can replace sodium ions in the soil through ion exchange, reduce the salt content of the soil, and alleviate the harm of salt to plants. improving fertilizer efficiency enhancing fertilizer solubility: calcium chloride is easily soluble in water, which can improve the solubility and fluidity of fertilizers in the soil, making the nutrients in the fertilizers more easily absorbed and utilized by plants. promoting the absorption of other nutrients: calcium elements can interact with other nutrients (such as nitrogen, phosphorus, potassium, etc.), promote the absorption and transportation of these nutrients by plants, and improve the utilization rate of fertilizers. prolonging the fertilizer efficiency of fertilizers: calcium chloride can form stable compounds in the soil, reduce the loss and volatilization of nutrients, and prolong the fertilizer efficiency period of fertilizers. other functions used as foliar fertilizer: calcium chloride can be sprayed on plant leaves as foliar fertilizer to quickly supplement the calcium nutrition required by plants, especially in the critical growth periods of crops, such as flowering stage and fruit expansion stage. compounding with other fertilizers: it can be compounded with nitrogen fertilizers, phosphorus fertilizers, potassium fertilizers, etc. to make compound fertilizers, meet the needs of plants for various nutrients, and improve the comprehensive effect of fertilizers. It should be noted that the application amount of calcium chloride in fertilizers should be reasonably determined according to factors such as soil conditions, crop types, and growth stages. Excessive use may lead to high soil salinity and affect plant growth. In addition, when calcium chloride is compounded with other fertilizers, attention should be paid to the compatibility between fertilizers to avoid chemical reactions that reduce fertilizer efficiency.

11

2025/06

The role of magnesium chloride in feed!

Magnesium Chloride (MgCl₂) in Feed: Functions and Considerations 1. Magnesium Supplementation to Prevent Deficiency Physiological Role: Magnesium is essential for energy metabolism (e.g., ATPase activation), bone development, nerve signaling, and muscle contraction. Applications: Ruminants (cattle, sheep): Prevents "grass tetany" (hypomagnesemia), especially in regions with low magnesium in pasture. Poultry & Swine: Supports bone health, eggshell formation (poultry), and reproductive performance. Bioavailability: MgCl₂ has high bioavailability, ideal for rapid magnesium supplementation. 2. Feed Processing Improvement Anti-caking agent: Enhances feed flowability and prevents moisture-induced clumping. Binder: May improve pellet stability during feed processing. 3. Electrolyte Balance Maintenance Synergy with Na⁺/K⁺: Regulates acid-base balance and mitigates heat stress (e.g., in high-temperature environments). Aquatic feed: Supplies magnesium ions for crustaceans (shrimp, crabs) to support molting and exoskeleton hardening. 4. Additional Functions Digestive aid: Moderate Mg²⁺ stimulates intestinal motility and digestion. Salt substitute: Partially replaces NaCl in low-sodium feeds to adjust palatability. Precautions Dosage: Overuse may cause diarrhea (especially in monogastric animals). Ruminant feed typically requires 0.2%-0.4% magnesium. Palatability: High concentrations may impart bitterness; ensure uniform mixing. Regulations: Comply with local standards (e.g., China’s Feed Additive Safety Guidelines). Storage: MgCl₂ is hygroscopic; store sealed to prevent clumping. Comparison of Magnesium Sources Source Bioavailability Cost Features MgCl₂ High Moderate Hygroscopic; suitable for liquids MgO Low Low Slow-release; common for ruminants MgSO₄ High Moderate Provides sulfur; may cause diarrhea

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2025/04